K.Andoetal.JournalofPowerSources390(2018)278–285
range.ThismaybeduetothelongerretentiontimeathigherSoC,applicationofdifferentialthermalvoltammetryasanin-depthstate-of-healthdi-
agnosismethodforlithium-ionbatteries,J.PowerSources307(2016)308–319,
whichproceedswiththereductiondecompositionreactiononthe
http://dx.doi.org/10.1016/j.jpowsour.2015.12.122.
anodesurface[17].
[8]V.A.Agubra,J.W.Fergus,Theformationandstabilityofthesolidelectrolytein-
terfaceonthegraphiteanode,J.PowerSources268(2014)153–162,http://dx.doi.
org/10.1016/j.jpowsour.2014.06.024.
4.Conclusion
[9]M.C.Smart,B.V.Ratnakumar,Effectsofelectrolytecompositiononlithiumplating
inlithium-ioncells,J.Electrochem.Soc.158(2011)A379–A389,http://dx.doi.org/
Inthisstudy,adV/dQcurveanalysiswasdevelopedforablended
10.1149/1.3544439.
[10]B.P.Matadi,S.Geniès,A.Delaille,C.Chabrol,E.d.Vito,M.Bardet,J.-F.Martin,
cathode.Byadaptingtheanalysisforlithium-ionbatterieswithblended
L.Daniel,Y.Bultel,IrreversiblecapacitylossofLi-Ionbatteriescycledatlow
cathodes,wequantitativelyevaluatedthedegradationfactorsunder
temperatureduetoanuntypicallayerhinderingLidiffusionintographiteelectrode,
differentcycletestconditions.Weconfirmedthattherearecleardif-
J.Electrochem.Soc.164(2017)A2374–A2389,http://dx.doi.org/10.1149/2.
0491712jes.
ferencesinthedegreeofcontributionofthedifferentdegradation
[11]I.Bloom,A.N.Jansen,D.P.Abraham,K.L.Gering,Differentialvoltageanalysesof
factorsdependingontheconditions.Forinstance,at0°C,althoughthe
high-power,lithium-ioncells1.Techniqueandapplication,J.PowerSources139
capacityreductionratewasalmostsameregardlessoftheSoCrange,
(2005)295–303,http://dx.doi.org/10.1016/j.jpowsour.2004.07.021.
[12]K.Honkura,K.Takahashi,T.Horiba,Capacity-fadingpredictionoflithium-ion
thedegradationmechanismsweredifferent.Forthe100%–0%SoC
batteriesbasedondischargecurvesanalysis,J.PowerSources196(2011)
range,thecathodeandanodedegradationandtheSEIformationoc-
10141–10147,http://dx.doi.org/10.1016/j.jpowsour.2011.08.020.
curredatthesametime,resultinginthereducedcapacity.Meanwhile,
[13]K.Honkura,T.Horiba,StudyofthedeteriorationmechanismofLiCoO/graphite
2
forthe100%–70%SoCrange,capacityreductionwasmainlyduetoSEIcellsincharge/dischargecyclesusingthedischargecurveanalysis,J.Power
Sources264(2014)140–146,http://dx.doi.org/10.1016/j.jpowsour.2014.04.036.
formation.Thenondestructivequantitativeevaluationofthedegrada-
[14]S.Watanabe,M.Kinoshita,T.Hosokawa,K.Morigaki,K.Nakura,Capacityfadeof
tionfactorsofbatteriesisusefultodeterminetherelationbetween
analysisofLiAlNiCoOcathodeforlithium-ionbatteriesduringaccelerated
y1?x?yx2
usageconditionsanddegradationfactors.Weexpecttoachieveaccu-calendarandcyclelifetests(surfaceanalysisofLiAlNiCoOcathodeafter
y1?x?yx2
cycletestsinrestricteddepthofdischargeranges),J.PowerSources258(2014)
rateacceleratedtestsandlifetimepredictionmethodsbasedonthis
210–217,http://dx.doi.org/10.1016/j.jpowsour.2014.02.018.
study.
[15]J.Belt,V.Utgikar,I.Bloom,CalendarandPHEVcyclelifeagingofhigh-energy,
lithium-ioncellscontainingblendedspinelandlayered-oxidecathodes,J.Power
Sources196(2011)10213–10221,http://dx.doi.org/10.1016/j.jpowsour.2011.08.
Acknowledgements
067.
[16]A.C.Arenas,S.Onori,Y.Guezennec,G.Rizzoni,Capacityandpowerfadecycle-life
ThisstudywaspartiallysupportedbyNewEnergyPromotion
modelforplug-inhybridelectricvehiclelithium-ionbatterycellscontaining
blendedspinelandlayered-oxidepositiveelectrodes,J.PowerSources278(2015)
Council(NEPC),Japan.
473–483,http://dx.doi.org/10.1016/j.jpowsour.2014.12.047.
[17]K.Ando,T.Matsuda,M.Myojin,D.Imamura,Calendardegradationmechanismof
AppendixA.Supplementarydata
lithiumionbatterieswithaLiMnOandLiNiCoMnOblendedcathode,ECS
240.50.20.32
Trans.75(2017)77–90,http://dx.doi.org/10.1149/07523.0077ecst.
[18]F.Izumi,K.Momma,Three-dimensionalvisualizationinpowderdiffraction,Solid
Supplementarydatarelatedtothisarticlecanbefoundathttp://dx.
StatePhenom.130(2007)15–2010.4028/www.scientific.net/SSP.130.15.
doi.org/10.1016/j.jpowsour.2018.04.043.
[19]T.Kobayashi,N.Kawasaki,Y.Kobayashi,K.Shono,Y.Mita,H.Miyashiro,A
methodofseparatingthecapacitiesoflayerandspinelcompoundsinblended
cathode,J.PowerSources245(2014)1–6,http://dx.doi.org/10.1149/07523.
References
0077ecst.
[20]Y.Shi,M.Zhang,D.Qian,Y.S.Meng,UltrathinAlOcoatingsforimprovedcycling
23
[1]Y.Makimura,S.Zheng,Y.Ikuhara,Y.Ukyo,Microstructuralobservationof
performanceandthermalstabilityofLiNiCoMnOcathodematerial,
0.50.20.32
LiNiCoAlOafterchargeanddischargebyscanningtransmissionelectron
0.80.150.052Electrochem.Acta203(2016)154–161,http://dx.doi.org/10.1016/j.electacta.
microscopy,J.Electrochem.Soc.159(2012)A1070–A1073,http://dx.doi.org/10.
2016.03.185.
1149/2.073207jes.[21]T.Ohzuku,M.Kitagawa,T.Hirai,Electrochemistryofmanganesedioxideinlithium
[2]S.Watanabe,M.Kinoshita,T.Hosokawa,K.Morigaki,K.Nakura,CapacityfadingofnonaqueouscellIII.X-raydiffractionalstudyonthereductionofspinel-related
LiAlNiCoOcathodeforlithium-ionbatteriesduringacceleratedcalendarmanganesedioxide,J.Electrochem.Soc.137(1990)769–775,http://dx.doi.org/
y1?x?yx2
andcyclelifetests(effectofdepthofdischargeincharge–dischargecyclingonthe10.1149/1.2086552.
suppressionofthemicro-crackgenerationofLiAlNiCoOparticle),J.Power[22]J.R.Dahn,PhasediagramofLiC,Phys.Rev.B44(1991)9170,http://dx.doi.org/
y1?x?yx2x6
Sources260(2014)50–56,http://dx.doi.org/10.1016/j.jpowsour.2014.02.103.10.1103/PhysRevB.44.9170.
[3]C.Wang,A.J.Appleby,F.E.Little,Electrochemicalstudyonnano-Sn,LiSnand[23]M.M.Thackeray,Manganeseoxidesforlithiumbatteries,Prog.SolidStateChem.
4.4
AlSipowdersusedassecondarylithiumbatteryanodes,J.PowerSources9325(1997)1–71.
0.1
(2001)174–185,http://dx.doi.org/10.1016/S0378-7753(00)00576-0.[24]X.-L.Wang,K.An,L.Cai,Z.Feng,S.E.Nagler,C.Daniel,K.J.Rhodes,A.D.Stoica,
[4]J.H.Ryu,J.W.Kim,Y.-E.Sung,S.M.Oh,FailuremodesofsiliconpowdernegativeH.D.Skorpenske,C.Liang,W.Zhang,J.Kim,Y.Qi,S.J.Harris,Visualizingthe
electrodeinlithiumsecondarybatteries,Electrochem.SolidStateLett.7(2004)chemistryandstructuredynamicsinlithium-ionbatteriesbyin-situneutrondif-
A306–A309,http://dx.doi.org/10.1149/1.1792242.fraction,Sci.Rep.2(2012)747,http://dx.doi.org/10.1038/srep00747.
[5]J.Vetter,P.Novák,M.R.Wagner,C.Veit,K.-C.M?ller,J.O.Besenhard,M.Winter,[25]S.J.An,J.Li,C.Daniel,D.Mohanty,S.Nagpure,D.L.Wood,Thestateofunder-
M.W.Mehrens,C.Vogler,A.Hammouche,Ageingmechanismsinlithium-ionbat-standingofthelithium-ion-batterygraphitesolidelectrolyteinterphase(SEI)and
teries,J.PowerSources147(2005)269–281,http://dx.doi.org/10.1016/j.itsrelationshiptoformationcycling,Carbon105(2016)52–76,http://dx.doi.org/
jpowsour.2005.01.006.
10.1016/j.carbon.2016.04.008.
[6]T.Waldmann,A.Iturrondobeitia,M.Kasper,N.Ghanbari,F.Aguesse,E.Bekaert,
[26]Y.Merla,B.Wu,V.Yufit,N.P.Brandon,R.F.Martinez-Botas,G.J.Offer,Novel
L.Daniel,S.Genies,I.J.Gordon,M.W.Loble,E.D.Vito,M.W.Mehrens,
applicationofdifferentialthermalvoltammetryasanin-depthstate-of-healthdi-
Review—post-mortemanalysisofagedlithium-ionbatteries:disassemblymetho-
agnosismethodforlithium-ionbatteries,J.PowerSources307(2016)308–319,
dologyandphysico-chemicalanalysistechniques,J.Electrochem.Soc.163(2016)
http://dx.doi.org/10.1016/j.jpowsour.2015.12.122.
A2149–A2164,http://dx.doi.org/10.1149/2.1211609jes.
[7]Y.Merla,B.Wu,V.Yufit,N.P.Brandon,R.F.Martinez-Botas,G.J.Offer,Novel
285 |
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