配色: 字号:
水性氟碳涂料及其应用
2013-03-26 | 阅:  转:  |  分享 
  


25



水性氟碳涂料及其应用

WaterborneFluorocarbonCoatingsandItsApplications





王玮,刘谦

(上海衡峰氟碳材料有限公司,上海200092)





摘要:V
£??p
¥Z
!9a¥Z?a 8¥y

?? è?Z
?s
£??p
¥?Z-?b

关键词:
£???A
£??p
y\¥



0引言

1Mc?
?tù
W[ ???s02? 

μK<¥''i$?Do
P
?VC?as¥??b[c

?
?t
??1$¥?p
9yN7 μ?+
ya

s¥??b?1VC
? !
1"-
g?

@?¥
?

aμAad
?
??p
?÷as¥?" ?a0·4?a

?a0?D0???????
P¨
p÷ VérB

ùù?VB?p
byN?p
üVíB¥?Z

S]ayyaB
a
F2?y?ù
5פ<W¥?¨b

"-·4£??[17%''
??1}V??3ú??

K?1?¨?ò??pá
?y?·4? ó?[''&7&?

QY
?í

??1}V?? Vè?%?yN

V<W?¨?ò??é?ò?
5×b

?t訥?p
?
^·4?¥
?"|
ììi
M¥

9<òS70$ è??μ??t
c
¥K?°m?

ì[μ·4T1?o饷4?c?
?tp
?ú

?%?c?
?tp
¥?¨
s?
B?¥K?b 7?
£?

?p
?1?p
?Z¥t
]?Z_b

1水性氟碳涂料研究与开发的重点

1.1保持溶剂型氟碳涂料的优点


£??p
A??eμ·4??p
¥?1a

?b7è?¥·4??p
D?Yp
¥?''?uY


^ μas¥??0??bT1·4?
?Fs?p
¥/

B}á??s9}á?
£??p
0?????D·

4??p
M?÷zb

1.2克服溶剂型氟碳涂料的缺点

"-·4?è?%??p
?¨?? μ?
?

? 

?Fsp

@yZ
?iò?K? 
?:

?¨
H
@yHq?¥?
1púpaD?? !z

¥?????×?^C 7
a??C` 
^$ê

?éù

e?B? 
·4?p
cμv
¥μè?

t 70$
ìaê?1?×]
H9 ?n''÷a ?n?

÷byN 7?¥
£??p
??? X?[
 ?4b

1.3满足目前外墙外保温体系的抗裂装饰要求

"-?:??8"?R?¨¥+?Z
T??1p

?V
???p


e?¥p
i1pμ F
?

e?

?b?:??"d¥?¨?·4??p
T1
e
?

?T) ??zaa?a
K?ab
ù?B?
£??p


''
&? ! F
1p? V[YV Fa>????p


£??
?¥pa"d¥Z
T3 %[]
Hr? F
?



e¥1pb

1.4适合于大面积的推广应用

???p

LC

£??
@y4vv??
@

yZE?
@yy\D?Y??B"dè
a??v
?¥

w<?¨b

2水性氟碳涂料的组成

?Y¥
£??p
¥¥Z?Vb

?V VnN¥Z?B???ií?vμsb??

e?¥¥Z?
?c¥??A?t
£

£??p


¥as??b



26



表1水性氟碳涂料的配方

e
¨
z

??A

t



£

ù4

2.1水性氟碳乳液

??òE
3???A
H¥
^L[#
?¨?8?]


L=?¨¥??A?2
iB?¥μs"- A

?r?B?¥?c
f ?/??Ai
àμ?
üA¥

a
-sM?
?"
£??¥???Zò?÷? ?μr

¥??ZE??¤C/
?
^BtCμZEo
b

2.1.1水性氟碳乳液制备方法

?!
£?c?
?tp
¥1o
^¤
£?c?
?

tb"-
£?c?
???1 ?μ??A#μ?s?

87
£·?¥c?
?t
?nb?!
£?c?
?t

¥/
??1μ?

??A
?E''[c?¥Y??té?1??

A
?|c??8D?c?Q?8
?¤c?
?

t?Ab?
^Kè

n¥ZEb

?a??E''5μ·4oé???c?
?t

?a
P·3¥c?
?t??4¥T¨/?1s?8

?YV??Q??¤c?
?t
£s?8bNZE?]??

A
?E???
?E V[YVd1?
?¥ZE

?
ê
aF?
??
??!c?
?tb?1c?
?t

??#??¥"?4
 V?¥o?b

è??
?E''s??
£M¥·μ??4¥?8A

ˉ?é?¥1?
?Eb
?
^ù?/c?
?t¥?1

ZE-B"-?v?C1?A
?
?9}¥t
]b

éYVs?8/
?''|c?
??xatA
as?

4a94a?ù4?
£?
aR¥
!!?s?7??


??A1p5?¤c?
??¥%±x?a
£??b

N/
?"-X?

P¨b

2.1.2水性氟碳乳液的种类

?
£?c?
?t¥2#? ? V?¤£
??

?£%?c?
?tp
b"-
g?

3á?g
r¥
£?

c?
?tp
 ''v
?1£
???°''?b0a%$


3avá
3?áSg
r¥c?
?t?AbB?£%

?c?
?tp
?
H?
3
?t? óQ?y7p

 μ÷D¥???a0???0?D??1 s?è

c?
?tp¥??μA1|
£?c?
?tp
??

£%?¥?
Tb£%?
£?c?
?tp
?? p


¥
?
T V|s1?Fs?
?Fs
?bN?| yc?

???Aμt??
9 μ??A¥??????M

e?9$<W
P¨b

????d
??A


£?d
??A''
&ü μ?z¥0???×??

?0
£?0ú??1?μb7d
?| y2é????

¥/
??? V[?Md
?''
&¥?t4?7O??Z

E1?e?y7
L=?¨??b?NZE¤?¥?A

??o
^| yc??c
B???v?P·

7O
P¨V??
ù?VC1?Yd
?1z?i?r?

?p
¥ú1pb

?
?Fsè?%???A

?b0
3 7?''&a?
?Fsè?%?

¥
£s??
??p
b''&7&2??? μ=??T¨

¥
Y
?vs0?8 &07&?
T
?
U
?!

?A?
?Fsp
¨''&7&
??
?9
^??
oY $5''&


?Y
?¥?92¥
tb%?4è¨T
£??¥

se
? V[¤?D·4?''&7&
??M
?¥??b"¨

?`ra
£Ce?íy?V
? ??:p

?? V¨

?á
?????a
b



O(C2H4O)nH


T




ù?
?Fs
£?p
Xμ?v¥?Z?c
 T?


E
r?[
??ùO1
@y-C?

?
àμ s8C
£?p

P¨ZL¥+?byN|
ì£

M???¤?Fs
i?? ó¥
£?p
b

è£
???Fs??A

vá
3ù?;&''''-&4&"
c?
?t
£s?

8
^ê?Y 7%''

tD
Jd
?J 1.."


s0
£ü
¥?tb??1.."¥D17%''?í

-WMoT¨<

P?
s?17%''¥1yNp

μ
z¥0
£?#as¥0??b
3¨?"
p
°

''??1ué?
÷ò
ka"e¥?2÷ò

Ba¨á
íè??° ú=£?;? ''53
"eV
?¥t

?a;6M?é?s?2Tpˉ?
S
?


a
ü?
£??p
 μas¥0??D0ò?7]
HT1

v
k"¥p??tX?
3?3b

¨NZE V?!?c
 T?
E
1¥c?

?Ab

é
i?? ó??A

?b0
3 ?¨?0?A
?/
???
?Fs V
i

?? ó¥1''&7&Dcè¥
?d[d??#
ed
?

?8
?t? ?
??e?1''&7&"$b''&7&Dd
?


?t
?¤? μ? T2¥
t??? (Ma



27



i
ü¥pa7t ??¥''&7&?d
??A5??s ?

¥?i
üpab''&7&"$p
?''
Pd
? ??8c


]?9
¥YV48. o?
kIa;


qˉ?b
?¨%?4
^$_$=?
?
3¥=?r

??d=
?=?raH=
?=?r?
?
ì??
?t?

A?¥?2?vè?
3%?? óQ?¨
1

_8"Q)?àêa??i×?b

¨?0?A
?E V?!?c
 T?
E
1

¥c??Ab

ê
£?????A

?
???AB???ú???
^? ?X???8

1$¥p
?1¨?p

?a?ta
£Ca
?
?]?b

?·4????p
¨[ ?T·4%8s_

%?4B?
^???A?
P¨
p ?ù
oμ_

Ip
A?
P¨
?
bK?ù?¥
£????8
?t

??s0=s0W V??
3? óQ?¥2?v?¨?s


£3¥?A?T%?4a?¨
?
V[×??

i?b
£????p
h

v
¥70$ V[|}

·4?p
úa?Dat b?
ey<
5×??¨b

M?÷<W¥?¨
5×?ZL¥
@yZE?-
£?

p
ù?¥£??
^?Fs
i?? ó¥??Ab

2.1.3氟含量的影响

??/
??
?¥$
?W?/
?
???¥?

?A
ù?K?¥?c
iBtμs?Mμ?
^?v

7O
L=?¨????z18C?p
¥as??b

????/
?/?¥??A¥?c
MμVv?¤¥

p
??μs??vbB?a1p
?
?c¥?c
ú


???¥?p
¥ò[??ü÷FasyN''
&?A?

¥?c
¥
 %?
??A¥K''¥Bt??b?]

??A?c
?
k 82T?V
?
Ub

表2不同产品中的氟含量

á1?c


S=
3

?S
??
3

F&v
3

°''vá
3

??c
?
Z?Dμ
??
k T?
E
b

VV V?òc??A?c
μs?v??
3áì

E?1
&/
?
á????i
]
?ts02#?

?
^LyNíEVs02? ???A¥ò[??

?V??
-
?[ μas??¥e ?s V?B??

A¥?c
úpa¥0??#+ò[??l1


£
L

?
??¥+?''óé?

e
Lé?1s

nVb

(1)1?0??

267I?p




a?p




?!¥"epX

%???×?ê7?p




¥"ept?μM?#;6


?
>X
üA7?¨°''4&??A?T¥
£??"

eˉVC?
?¥
?b


0
£?

V?
£?|??¥"e"?rT V?



a



p


C?7



a



?p
V
?5''

àμM?

?
?
ì¨?ìET?" ??
k?C




?7



5


àμ??ù5b


×??

V??A¥s3? Vn



K1×??¥?

s3b

VY??!?
k
kV
ü



a



a



?p???l

?Q



0Y??!Q
? VrQpV
?
àμ

??ù5b

表3各乳液涂料及涂膜性能测试

_?=?_?S

















=J&#

0·4?Q

Y?#

s3?¥5(5%"

2? g£μμ
üA+?
àμ

μμ
üA+?
àμ

]μμ? V"+?
àμ

0ê??

:|3

?μμ? V"
àμ

)40
i?EíM?íM??s?íM?

00??

/B0)
i?E?
?
?±?M

0?
£¥E"?aW ?aW ??íM?

0
£?

0
£????
?íM?


A?" ?¥?E?" ??
??
?
?
z

0??
>;
q
267I





28



=J&?!?
k



a



a



??μ



0=J&?!

Q
? VrQ[
¤í·4??p

£üb

V0
?a
k ? A



a




£??p
0
?a??

?z -
^0a??




?p
¥C?C`7

oμ



íM?? s
a
ü
N??A?!¥
£??

p
 μa
¥0?D0??b

V0ê??? ? A



?p
0ê?Kz7



p
?



p
Q-



?p
??5K1
ü

Ab

2.2高性能的颜料

?p
1?0??p
è?¥
?ì0ò?z¥t


?A?
?@?p
éù??
P¨¥1pb
L?á
ìê4


+????¥ít
?μt
é?0??
Lb


L
H¨úa,?§é?b|ò?t
?

?;&''''-&

4&??A?as?p?
k"

?????úa,

?§/sY??ü÷òa?μ¥M?büI÷òa2

T?Vb

VV2T V?(Lít
?μ?&M???v

V
ü(Lít
¥0,?;??ùùv?μt

6?

(Lít
¥0???0
?a?91B?μt

?4

[1E1

?@?p
?0?¥+?ê4(Lít


9}.dμt
dèA1b

表4选用典型无机颜料及有机颜料的氟乳液耐候性实验结果

t
=???e£?e?M£M?| ?e
s

μ0ò

£

μ¥%

,

μ
y]


s

?&

?43

+?íM

?

+?íM

?

μ V
jM

?

+?íM

?

?
üAM

?

+?íM

?

+?íM

?

?×M??×M?

?
üA

M?



???p
?
H?31
@y
H?T_
he?á


?rTp
?T
HB??F?
hx??
£?p
?


?t
¥U??
àμ·4?
??
1zyNB?á


?t
ê4
Hwi
P¨0?Da
K¥U?
hx?"|

???Y??pa8"¥??-á
?t
¥0????

0?D?+Y
^0a?b?T�Y
hxpa?^M

à b
hx¥?
???0a??z7/??b

7
£???
6B??1t
ü
^è;t
è;t


?1
^?í?? ?-5J0
e"?t


F?
L=?¨?0???zb

yN1
¥?
£??p
as¥0??e
¥ê

4
B?wi
P¨(Lít
U?
hxè;t


b

3水性氟碳涂料的制备

3.1水性氟碳涂料制备

ê4
K?1¥??A?t
[a1
????ù

4aù·4at
p
¥Z?¥c
? ú?¨??
k

E?y
í
£ü
k ??ê''¥Zꨥ??
k

V1- 




b I3¥y
í1"??A#£ù?A$t


%A
&A
''A
(??ù4 ".1


)h?494+94,ù·4-ù·4

.?ù4/?
As?40
@ü4ˉ?ê )4%?

?
¨
£?@b?A
£ü′?v
B?
k
e

ù4?vù44ìE¥
? nV
b

YV

?
k¥F?¤
??]¥1¥p


é??"ié?p?4a0
£?a0
??a0a??0

ê??[1
í¥_?Kaê?''¥Z1??A


??Aí(Lt
A
1A


1??ù4h?4941

941ù·41ù·41

?ù4?
As?4
@ü4?1


£b


L8?
£?p
¥''¥Z??[a1?¥?á


?p
?è;p

H??+???¨A
??¥Z
H?

?Ac
1£ù?Ac
1[£M?¥%

c
?{? ?bá
?t
?è;t
¥
YV¥
H¥{?

?
L 8???á
?t
1_è;t
1

j
?dA
ù4
?Mb

3.2成品水性氟碳涂料性能

[vá
3¥£
???Fs??A;&''''-&4&"
c

??A?

?¥1??¥
£??p
''???Vb

üV''
3
?"?
Zp
ù?
??
k2T (r?



?1p
.à÷z nM1_?á
b?μBtl¥+

? 
0Uê??D
L?′?1 
0|y? o?

?Ií?ax??ph
?M?)br?


ù?¥1pb

3.3一些其他功能氟碳添加剂的使用

?T
£ù4?é0Uê

.d?p
¥1±???1
^G ??
??V
???

¥+?/?V
?

£b?
L=?¨?1±???v

v??b



29



表5水性实体色氟碳涂料配方筛选正交试验表L16(2

15

)

/P"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

"#$%&''()+,-./-

表6水性氟碳漆基本性能

·S


?b["?¨S

''$8''$8''$8

p?4"
jEü?t? (Báí?μü?t? (Báí?μ

1
q a??0?
(#5i?


@y?(#5i
?p
?íp?

??×??(#5i?Mé

?2
HW V?
(#5i?I?I

0ê??2? g£
k?
=??
=?

0!
??(#5i??

0Uê?(#5i??

0?M?+(5iQ?ìísèQ?ìísè

0·4?=J&#Q?
]?#Q?
]?

0
??)40IísèIísè

0a?(#5iIísèIísè

0
£?(#5iIísèIísè

0|y? o??(#5iIí?ax??ph
?M??)
>;?)



 ?¥ù?|?Xü?i??1ey?paV


?¥8".d?paV
?1

£?¤(?v? ?


?^¤(VayNíE
LCvE?Ra]¥o?
£

?

71±p??b
x?paV
?T
£4
^B???ú??@F

4e¨?1sap
?vá ?1p
?V?

?
x?paV
?T
£4?v
?paV
???±4


?
??
x0¥T
£?2μ ???a??¥1±b?

¨V
?T
£4?ípaV
?+
y¥T
£?
P? ?
£?^ (

1s?paV
?iμ
HW|V
?¥??
!?êr

?1±¥?rb

?,
ü/
?¥?é

Sù|?V
W@ 7
S
£??p
é?
ù

?i?|
,
ü?
#,
ü/
?
£??p
é?


??b



30



?¨,
ü?
¥

£??éo
_ON
,?

LQ

qr[
,?Lo¥Q

qr

_¥+???A?¥? y0?D??z?

?·T;b?¥??eT¨|
?a
]o?D? X

?F??B?ú??¥?p
éB?4ú

£??

p
¥ò[??b

???¨,
ü/
?μr14ú
?AD?Aa?AD

t
a?ADA
 R ì-W¥?
?2? ??
H
2??

2v?4ú
p¥<?0!
??b

4水性氟碳涂料的应用


£??p

L=¨??1T1é
p

epa

?`r¥]apa
P¨b_
he/
?Z
?[
£?_
h

e?p
??¥_
heD
h
?eM1???#?4


X
Es¤íO_
he1
h
?e÷ a
]?Nì? ÷a
@

yùa¥?
a
!9
??
?àa????
??F
?

?Z?p
?
< ?¥w?T¨b

31·¥
^_
he-
^
£?_
he
@y?


hx¥?_?
ù5
^B?ˉ¥/
?45b?ù4aV


? e?ù4a?
As?ù4[#8"¥?2
??
hx¥

?_?
μ"?v¥?YbüVQˉ¥
LCXü??

13 %

£??_
he?á
?t
¥?
a?_ù5


P
£?_
he¥w<?¨÷F?
?b


3¥
£?_
hey\?/


b":8V
?
??té¨
a?¥A??
A?:

8¥
???J


?A?H0??2a?
!91p?séL

iL
???1


?''??H0°à:8ü?aü?¨

£NN[=


?
£??_
he¨;
?H0


?)?''¨??H0??
H[
a?y ?

/?



?
£??_
he¨>p
?¥?





£??_
he
?
@y_?


?¥???a) ?b

V[ A??y\?''&7&2??p
¥_
he
à

μ''é¥uY
@y
?
^i?l¥431??¥

ü???
^/?2?_
hey?4S¥?''eyb[/
^


Z??¥''675#8ZEb

1
r?éù¥

e??]a"¥
£??p
B?

?
|
?°¤T1?Bpa
P¨b71
r?ú

e?B

?1
P¨¥?¥H0?>13 % F
??1¥

¨ F
H0????pbüVv
¥ù??y?
Llá


ì4
?y\ nV
?3 %?]V
?¥p
ù5 



£?_
he 
/?
L8? 

í`rp
b

-
^
£?_
he?¨
???p V[h
 F
?

�?
6??¨l ?
°¥
@yZ
T V[vvh
2

?_
he???ü?¥1pby?
L è??¨??

y\é?
@y¥
£?_
hey\v1eL¥]
H?? V

[r??
?2?_
he¥rTb

5水性氟碳涂料的工程应用案例

5.1四方台大桥


1Z
?vB
^áSú?1u?y¥
nV
^| ?Ba


??~
?BVv t?| ?
^BB
ó1C???`r

2b?B1
?
ó
?
ì
??`r2?
| ?B
ó%

2B8
óD?
:_?|?
?
óí2a
ó
|?
T

???8"bM_WW:^
1Z
?vB?¨?

?
3''675#,?ê? F 7

£??p
p
"d


??p
"dt?1á
?è;a?p
9
?1

£N




@yyù1?°p

??VN



_


b?Bp
à?XμB
HW"-?4

á?b

5.2淮南煤仓(13600m

2

)


? ?¥ìa/ò?ê?8?x?ù?z V[

?è''$8
£??p
0?D??za0Uê?a

s¥+?bM??
3¥''$8???¨

??êé2
? ?¥B?%
???y??¨''675#,?

ê? F 7

£??p
p
"dt? ? ?
''?a

''
L80 ?a''
L8a?t?9¥p

?

N



b?y?"-?4xíM?b

5.3同济大学城规学院

]6vD[
!97???Z=?]6ì?DyT1

]6vD¥×?y?-B?¨
''675#4
£?
í`

rp
"dp

?1N



b?y?òaYò?

μ\
?VC ?b

5.4杭州某工程的水性仿铝板涂装,与油性仿铝板

的对比分析

?y?["??¨
''VWJU#8y\''?¨

''$8
£?á
?é??p
1
?pa¥_
hey\


?v?N



b7ú

e_
he''675#?:?

p
"d''·4?
?Fsè?%??p
_
hey\

''?¨''$4"
 Vè?%??p
1
?pa¥_
h

ey\b
?p
"d? μ?z¥
he:rTb?V

 8¥?TV??·4??p
31 F
?ì?7


£??p
B??31 V[?¨???p¥Z
T3 %b

]
H
£?_
he1?2?_
heìa
@y÷FZL0

Uê?÷


31



表7水性氟碳涂料的3种涂装工艺

y\??¨?
?
+?y\F??¨+??¨
5×


£? Fa>?

]?`r¥?????]?`r=

¥<a
14úpa¥?" ?

F
süH04ú:
?¥ü??ù¥ F
rT

/?
??H

0

"/???3]? F
? ?¥?Y

?p

4úpa]1a

e?4μé?¥V
?

?
??%±
?


£?á
??p
1a μú

e??ú0??

''675

#8ú



eá
?é

?
£??

p
"

d


£??w;1/aá
??
hxt
4ú]1?

(- F
süH0

(-/?
(-??H0

#$8?p

#$8???p

17$séH

''$8
£?á
??
?

''$8
£??w;

8
£?>?


£C?



é?~?μ

C}?
p

é F 7


^b±?1

?''??^


@ya
@yù



ú?



La÷


La??a

úayya

?)
g?a

??v?


g?yya

B
aY
?

?


£? Fa>?

]?`r¥?????]?`r=

¥<a
14úpa¥?" ?

???p

4úpa]1a

e?4μé?¥V
?

?
??%±
?

''675

#,?ê

? F 7



£??

p
p


"d


£??p
1a μú

e??ú0??

(- F
süH0

(-/?


#$/???p





''$8
£??
?

8
£?>?


£C?



ò
L0 A


pé?ê

? F 7


?¥?1

?''?N1

ú

v?yy

=?:ú

OBaY


?a÷


Laì\?


£? Fa>?

]?`r¥?????]?`r=

¥<a
14úpa¥?" ?

''675

#4
£?

`rp


"d


£??w;

?ê???μr1:8üé:8¥
P


p

''$8
£??ê??
?

8
£?ú
1i>?


£C?
F?a!?




?''??8

C?e
S

?
·]
£?

z
@yy\

e?ap
Z

La^
@y

?¨?Y

òaòa

?+
??

¥
5×?

Dá
?aj

e:r

??z¥

¥?



6水性氟碳涂料的发展趋势


£??p
w<?¨?X !
[/Hq


ì?


?"| ?
3iìa¥1i
M9<1ooμB?

11oü
^1| ?1-b| ??ù? 7?B?[
£1

·4¥
£??p
\é<_ì??¨í]??

?SE?Dy?áE?p????¥á<Z_bV''


3ù???¥
£?,
ü?p
_?
? V
üμ??t

è?
v???SE??¥=:p
¥/
?1p
3

áa
P¨?V?? (??ê?ìa !
w<?¨¥
n1

Hqb


ü6?


£??p
¥Nìv???2??p
¥Nì

?1aé¥Adp
ú~70 o????ú?

aéAdp
~b???p
 μ?0??a0Uê

??as+?V?N1sü6rm
üAú?B?¥


?p
b



@yZL

??
£??p
¥
@yy\DB?
£?p
y\M

]??
w<?¨¥4?^$
@y?ê
?¤
s9L

?£
@yé
b


< ?¥
g?

íM ?yy
g?f
??Z+Y
^úayyaú)tMa


gúOa
^B
?
?M[¥
?ìbyy?:

úSp
¥3p9 9 è??
#÷Mí

?yy?:p

ü???0 o???A?B[


?
?y?b?üó
£??p
¥ 7?{ ?



914úáS¥yyp
á??QT

Db

??ta
][#| ?? V???Za
M¥F<

??
? ??p
¥ù??
£?ù?A???1£

?b?"÷1ü6??÷F??
P¨÷FL ?¥÷

1??¥
£??p
|?÷ y1Cò?311?



e¥p

5×b


?<S¥??


£??p
¥?<S9é?
?9
H¨

?"M

1S¥??
£??p
¥?ZA|é?B??Z¥?á

ùb



献花(0)
+1
(本文系独狼书屋首藏)